Annealing ambient in integrated circuit interconnects

ABSTRACT

A method of manufacturing an integrated circuit is provided having a semiconductor substrate with a semiconductor device. A device dielectric layer with an opening provided therein is formed on the semiconductor substrate. A barrier layer lines the channel opening. A conductor core fills the opening over the barrier layer. The integrated circuit is annealed in an atmosphere containing ammonia. This results in reduced hydrogen accumulation, improved bonding, and reduced electro-migration.

TECHNICAL FIELD

The present invention relates generally to semiconductor technology and more specifically to reducing hydrogen in the barrier layer to channel interface.

BACKGROUND ART

In the manufacture of integrated circuits, after the individual devices such as the transistors have been fabricated in and on a semiconductor substrate or wafer, they must be connected, or “wired”, together to perform the desired circuit functions. This interconnection process is generally called “metallization” and is performed using a number of different photolithographic, deposition, and removal processes to create contacts to the transistors, wire/channels to the contacts, and vias interconnecting the channels where there are more than one level of channels.

There are a number of different metallization techniques, but generally, a device dielectric layer is deposited over the transistors, openings are formed through the device dielectric layer down to transistor junctions and gates, and the openings are filled with a conductive metal to form contacts.

In one technique called the “single damascene” or “single inlaid” process, the formation of the first channels starts with the deposition of a thin first channel stop layer on the device dielectric layer. The first channel stop layer is an etch stop layer which is subject to a photolithographic processing step which involves deposition, patterning, exposure, and development of a photoresist, and an anisotropic etching step through the patterned photoresist to provide openings to the contacts. The photoresist is then stripped.

A first channel dielectric layer is formed on the first channel stop layer. Where the first channel dielectric layer is of an oxide material, such as silicon oxide (SiO₂), the first channel stop layer is a nitride, such as silicon nitride (SiN), so the two layers can be selectively etched. The first channel dielectric layer is then subject to further photolithographic process and etching steps to form first channel openings in the pattern of the first channels. The photoresist is then stripped.

An optional thin adhesion layer is deposited on the first channel dielectric layer over the entire semiconductor wafer and lines the first channel openings to ensure good adhesion of subsequently deposited material to the first channel dielectric layer. The adhesion layer is a metal such as tungsten (W), titanium (Ti), or tantalum (Ta).

High conductivity metals, such as copper (Cu), diffuse easily through dielectric materials such as silicon oxide and silicon nitride. This diffusion can result in a conductive buildup and cause short circuits in the integrated circuits. To prevent diffusion, a diffusion barrier is deposited on the adhesion layer. For copper conductor materials, the diffusion barrier layer is composed of materials such as tantalum nitride (TaN), titanium nitride (TiN), or tungsten nitride (WN).

However, these nitride compounds have relatively poor adhesion to copper and relatively high electrical resistance so they are problematic. For simplicity, the adhesion and barrier layers are sometimes collectively referred to as a “barrier” layer herein.

For conductor materials, such as copper and copper alloys, which are deposited by electroplating, a seed layer is deposited on the barrier layer and lines the barrier layer in the first channel openings to act as an electrode for the electroplating process. Processes such as electroless, physical vapor, and chemical vapor deposition are used to deposit the seed layer.

A first conductor material is electroplated on the seed layer and fills the first channel opening. The first conductor material and the seed layer generally become integral, and are often collectively referred to as the conductor core when discussing the main current-carrying portion of the channels.

A chemical-mechanical polishing/planarization (CMP) process is then used to remove the first conductor material, the seed layer, and the barrier layer above the first channel dielectric layer so the materials and layers are coplanar with the dielectric layer. The CMP process leaves the first conductor “inlaid” in the first channel dielectric layer to form the first channels. When a thing dielectric layer is placed over the first channels as a final layer, it is called a “capping” layer and the single damascene process is completed. When the layer is processed further for placement of additional channels over it, the layer is a via stop layer.

In another technique called the “dual damascene” or “dual inlaid” process, vias and channels are formed at the same time, generally over a completed single damascene process series of first channels. Effectively, two levels of channels of conductor materials in vertically separated planes are separated by an interlayer dielectric (ILD) layer and interconnected by the vias.

The initial step of the dual damascene process starts with the deposition of a thin via stop layer over the first channels and the first channel dielectric layer if it has not already been deposited as a capping layer. The via stop layer is an etch stop layer which is subject to photolithographic processing using a photoresist and anisotropic etching steps to provide openings to the first channels. The photoresist is then stripped.

A via dielectric layer is formed on the via stop layer. Again, where the via dielectric layer is of an oxide material, such as silicon oxide, the via stop layer is a nitride, such as silicon nitride, so the two layers can be selectively etched. The via dielectric layer is then subject to further photolithographic process using a photoresist and etching steps to form the pattern of the vias. The photoresist is then stripped.

A second channel dielectric layer is formed on the via dielectric layer. Again, where the second channel dielectric layer is of an oxide material, such as silicon oxide, the via stop layer is a nitride, such as silicon nitride, so the two layers can be selectively etched. The second channel dielectric layer is then subject to further photolithographic process and etching steps to simultaneously form second channel and via openings in the pattern of the second channels and the vias. The photoresist is then stripped.

An optional thin adhesion layer is deposited on the second channel dielectric layer and lines the second channel and the via openings.

A barrier layer is then deposited on the adhesion layer and lines the adhesion layer in the second channel openings and the vias.

Again, for conductor materials such as copper and copper alloys, a seed layer is deposited on the barrier layer and lines the barrier layer in the second channel openings and the vias.

A second conductor material is electroplated on the seed layer and fills the second channel openings and the vias.

A CMP process is then used to remove the second conductor material, the seed layer, and the barrier layer above the second channel dielectric layer to form the second channels. When a layer is placed over the second channels as a final layer, it is called a “capping” layer and the dual damascene process is completed.

The layer may be processed further for placement of additional levels of channels and vias over it. Individual and multiple levels of single and dual damascene structures can be formed for single and multiple levels of channels and vias, which are collectively referred to as “interconnects”.

The use of the single and dual damascene techniques eliminates metal etch and dielectric gap fill steps typically used in the metallization process for conductor metals such as aluminum. The elimination of metal etch steps is important as the semiconductor industry moves from aluminum (Al) to other metallization materials, such as copper, which are very difficult to etch.

A major problem occurs during the annealing of conductor core materials, such as electroplated copper. As part of the process, an ambient reducing atmosphere, often referred to as a “forming gas”, is used to prevent oxidation from occurring. Conventional annealing processes utilize an ambient that is a combination of nitrogen (N₂) and hydrogen (H₂) gas. Unfortunately, hydrogen molecules readily diffluse into copper films, particularly along grain boundaries. The resulting accumulation of hydrogen at or near the interface between the barrier layer and the conductor core adversely affects the bonding at the interface and may play a role in enhancing electro-migration (EM) of the copper conductor.

Electro-migration occurs when weak bonding at the interface between the barrier layer and conductor core permits atomic movement of conductor material under the influence of electric current flow. This atomic movement is particularly problematic with copper conductor cores and promotes void formation in the copper along the barrier layer. In the narrow confines of a via, the problem posed by the voids is magnified. The voids nucleate, increasing in size and raising via resistance until, ultimately, they result in open circuits that can corrupt data and render the entire circuit unusable.

Solutions to these problems have been long sought but have long eluded those skilled in the art.

DISCLOSURE OF THE INVENTION

The present invention provides a method for manufacturing an integrated circuit having a semiconductor substrate with a semiconductor device. A dielectric layer is formed on the semiconductor substrate and an opening is formed in the dielectric layer. A barrier layer is deposited to line the opening and conductor core is deposited to fill the channel opening over the barrier layer. The integrated circuit is annealed in an atmosphere containing ammonia. This results in reduced hydrogen accumulation, improved bonding, and reduced electro-migration.

The above and additional advantages of the present invention will become apparent to those skilled in the art from a reading of the following detailed description when taken in conjunction with the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 (PRIOR ART) is a plan view of aligned channels with a connecting via;

FIG. 2 (PRIOR ART) is a cross-section of FIG. 1 (PRIOR ART) along line 2—2; and

FIG. 3 is a cross-section, similar to that shown in FIG. 2 (PRIOR ART), of a semiconductor wafer in accordance with the present invention.

BEST MODE FOR CARRYING OUT THE INVENTION

Referring now to FIG. 1 (PRIOR ART), therein is shown a plan view of a semiconductor wafer 100 including a silicon semiconductor substrate (not shown) having as interconnects first and second channels 102 and 104 connected by a via 106. The first and second channels 102 and 104 are respectively disposed in first and second channel dielectric layers 108 and 110. The via 106 is an integral part of the second channel 104 and is disposed in a via dielectric layer 112.

The term “horizontal” as used in herein is defined as a plane parallel to the conventional plane or surface of a wafer, such as the semiconductor wafer 100, regardless of the orientation of the wafer. The term “vertical” refers to a direction perpendicular to the horizontal as just defined. Terms, such as “on”, “above”, “below”, “side” (as in “sidewall”), “higher”, “lower”, “over”, and “under”, are defined with respect to the horizontal plane.

Referring now to FIG. 2 (PRIOR ART), therein is shown a cross-section of FIG. 1 (PRIOR ART) along line 2—2. A portion of the first channel 102 is disposed in a first channel stop layer 114 and is on a device dielectric layer 116, which is on the silicon semiconductor substrate. Generally, metal contacts are formed in the device dielectric layer 116 to connect to an operative semiconductor device (not shown). This is represented by the contact of the first channel 102 with a semiconductor contact 118 embedded in the device dielectric layer 116. The various layers above the device dielectric layer 116 are sequentially: the first channel stop layer 114, the first channel dielectric layer 108, a via stop layer 120, the via dielectric layer 112, a second channel stop layer 122, the second channel dielectric layer 110, and a capping or via stop layer 124.

The first channel 102 includes a barrier layer 126, which could optionally be a combined adhesion and barrier layer, and a seed layer 128 around a conductor core 130 having a boundary 127. The second channel 104 and the via 106 include a barrier layer 132, which could also optionally be a combined adhesion and barrier layer, and a seed layer 134 around a conductor core 136 having a boundary 133. The barrier layers 126 and 132 are used to prevent diffusion of the conductor materials into the adjacent areas of the semiconductor device. The seed layers 128 and 134 form electrodes on which the conductor material of the conductor cores 130 and 136 is deposited. The seed layers 128 and 134 are of substantially the same conductor material as the conductor cores 130 and 136 and become part of the respective conductor cores 130 and 136 after the deposition.

A major problem occurs during the annealing of conductor core materials, such as electroplated copper. As part of the process, an ambient reducing atmosphere, often referred to as a “forming gas”, is used to prevent oxidation from occurring. Conventional annealing processes utilize an ambient that is a combination of nitrogen (N₂) and hydrogen (H₂) gas. While not clearly understood, it appears that some concentration of hydrogen in the nitrogen carrier, often known as “forming gas” migrates readily into the conductor core, most likely along the grain boundaries, and accumulates in the conductor material at or near the barrier layer interface. This results in significant amounts of hydrogen at the boundaries 127 and 133, which may weaken the interface bond between barrier layers and copper conductor cores, which may result in increased electro-migration (EM).

Electro-migration occurs when weak bonding at the interface between the barrier layer and conductor core permits atomic movement of conductor material under the influence of electric current flow. This atomic movement is particularly problematic with copper conductor cores and promotes void formation in the copper along the barrier layer. In the narrow confines of a via, the problem posed by the voids is magnified. The voids nucleate, increasing in size and raising via resistance until, ultimately, they result in open circuits that can corrupt data and render the entire circuit unusable.

Referring now to FIG. 3, therein is shown a cross-section similar to that shown in FIG. 2 (PRIOR ART) of a semiconductor wafer 200 of the present invention. The semiconductor wafer 200 has first and second channels 202 and 204 connected by a via 206. The first and second channels 202 and 204 are respectively disposed in first and second dielectric layers channel 208 and 210. The via 206 is a part of the second channel 204 and is disposed in a via dielectric layer 212.

A portion of the first channel 202 is disposed in a first channel stop layer 214 and is on a device dielectric layer 216. Generally, metal contacts (not shown) are formed in the device dielectric layer 216 to connect to an operative semiconductor device (not shown). This is represented by the contact of the first channel 202 with a semiconductor device gate 218 embedded in the device dielectric layer 216. The various layers above the device dielectric layer 216 are sequentially: the first channel stop layer 214, the first channel dielectric layer 208, a via stop layer 220, the via dielectric layer 212, a second channel stop layer 222, the second channel dielectric layer 210, and a next channel stop layer 224.

The first channel 202 includes a barrier layer 226 and a seed layer 228 around a conductor core 230 having a boundary 227. The second channel 204 and the via 206 include a barrier layer 232 and a seed layer 234 around a conductor core 236 having a boundary 233. The barrier layers 226 and 232 are used to prevent diffusion of the conductor materials into the adjacent areas of the semiconductor device. The seed layers 228 and 234 form electrodes on which the conductor material of the conductor cores 230 and 236 is deposited. The seed layers 228 and 234 are of substantially the same conductor material of the conductor cores 230 and 236 and become part of the respective conductor cores 230 and 236 after the deposition.

By providing ammonia gas in the nitrogen carrier gas, at concentrations from 5% ammonia up to 100% ammonia by volume, it is believed that the hydrogen at boundaries 227 and 233 can be substantially eliminated, because the larger ammonia molecules do not diffuse along the grain boundaries as does the hydrogen. This would provide the ability to maintain go the conductor core material in a reduced oxygen state while preventing the accumulation of hydrogen as shown in FIG. 2 (PRIOR ART).

In various embodiments, the diffusion barrier layers are of materials such as tantalum (Ta), titanium (Ti), tungsten (W), alloys thereof, and compounds thereof. The seed layers (where used) are of materials such as copper (Cu), gold (Au), silver (Ag), an alloy thereof, and a compound thereof with one or more of the above elements. The conductor cores with or without seed layers are of conductor materials such as copper, aluminum (Al), gold, silver, an alloy thereof, and a compound thereof. The dielectric layers are of dielectric materials such as silicon oxide (SiO_(x)), tetraethoxysilane (TEOS), borophosphosilicate (BPSG) glass, etc. with dielectric constants from 4.2 to 3.9 or low dielectric constant dielectric materials such as fluorinated tetraethoxysilane (FTEOS), hydrogen silsesquioxane (HSQ), benzocyclobutene (BCB), TMOS (tetramethoxysilane), OMCTS (octamethyleyclotetrasiloxane), HMDS (hexamethyldisiloxane), SOB (trimethylsilil borxle), DADBS (diaceloxyditerliarybutoxsilane), SOP (trimethylsilil phosphate), etc. with dielectric constants below 3.9. The stop layers and capping layers (where used) are of materials such as silicon nitride (Si_(x)N_(x)) or silicon oxynitride (SiON).

While the invention has been described in conjunction with a specific best mode, it is to be understood that many alternatives, modifications, and variations will be apparent to those skilled in the art in light of the aforegoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations that fall within the spirit and scope of the included claims. All matters hither-to-fore set forth or shown in the accompanying drawings are to be interpreted in an illustrative and non-limiting sense. 

The invention claimed is:
 1. A method of manufacturing an integrated circuit comprising: providing a substrate having a device provided thereon; forming a dielectric layer on the substrate; forming an opening in the dielectric layer; depositing a barrier layer to line the opening; depositing a conductor core over the barrier layer to fill the opening and connect to the device; and annealing the integrated circuit in an ammonia containing anneal atmosphere to provide ammonia molecules at grain boundaries of the conductor core.
 2. The method of manufacturing an integrated circuit as claimed in claim 1 wherein the anneal atmosphere contains ammonia from 5% ammonia to 100% ammonia by volume.
 3. The method of manufacturing an integrated circuit as claimed in claim 1 wherein the anneal atmosphere uses nitrogen as a carrier gas.
 4. The method of manufacturing an integrated circuit as claimed in claim 1 wherein depositing the barrier layer deposits a pure refractory metal.
 5. The method of manufacturing an integrated circuit as claimed in claim 1 wherein depositing the barrier layer uses a material selected from a group consisting of tantalum, titanium, tungsten, an alloy thereof, and a compound thereof.
 6. The method of manufacturing an integrated circuit as claimed in claim 1 wherein depositing the conductor core deposits a material selected from a group consisting of copper, aluminum, gold, silver, an alloy thereof, and a compound thereof.
 7. A method of manufacturing an integrated circuit comprising: providing a semiconductor substrate having a semiconductor device provided thereon; forming a dielectric layer on the semiconductor substrate; forming an opening in the dielectric layer; depositing a barrier layer to line the opening; depositing a conductor core over the barrier layer to fill the opening and connect to the semiconductor device; and annealing the integrated circuit in an ammonia-containing atmosphere ambient to provide ammonia molecules at grain boundaries of the conductor core.
 8. The method of manufacturing an integrated circuit as claimed in claim 7 wherein the anneal atmosphere contains ammonia from 5% ammonia to 100% ammonia by volume.
 9. The method of manufacturing an integrated circuit as claimed in claim 7 wherein the anneal atmosphere uses nitrogen as a carrier gas.
 10. The method of manufacturing an integrated circuit as claimed in claim 7 wherein depositing the barrier layer deposits a pure refractory metal.
 11. The method of manufacturing an integrated circuit as claimed in claim 7 wherein depositing the barrier layer uses a material selected from a group consisting of tantalum, titanium, tungsten, an alloy thereof, and a compound thereof.
 12. The method of manufacturing an integrated circuit as claimed in claim 7 wherein depositing the conductor core deposits a material selected from a group consisting of copper, aluminum, gold, silver, an alloy thereof, and a compound thereof. 